2, 4-D Amine 4

Shredder® Amine 4

ACTIVE INGREDIENT:

Dimethylamine salt of 2,4-Dichlorophenoxyacetic acid *..............................47.3% OTHER INGREDIENTS : ......................................................................................... 52.7% TOTAL......................................................................... ...100.0%

* Isomer specific by AOAC Method No. 6.275 (13th Edition) 1980
* 2,4-Dichlorophenoxyacetic acid equivalent 39.3%. Contains 3.8 lbs. of 2,4-Dichlorophenoxyacetic

acid per gallon.

KEEP OUT OF REACH OF CHILDREN DANGER PELIGRO

Si usted no entiende la etiqueta, busque a alguien para que se la explique a usted en detalle. (If you do not understand the label, find someone to explain it to you in detail.)

PRECAUTIONARY STATEMENTS HAZARDS TO HUMANS AND DOMESTIC ANIMALS

DANGER

Corrosive. Causes irreversible eye damage. Harmful if swallowed. Do not get in eyes, on skin or on clothing. Avoid breathing spray mist.

FIRST AID
NOTE TO PHYSICIAN: Probable mucosal damage may contraindicate the use of gastric lavage.

IF IN EYES: Hold eyelids open and rinse slowly and gently with water for 15-20 minutes. Remove contact lenses, if present, after the first 5 minutes; then continue rinsing. Call a poison control center or doctor for treatment advice.
IF SWALLOWED: Call a poison control center or doctor immediately for treatment advice. Have person sip glass of water if able to swallow. Do not induce vomiting unless told to by a poison control center or doctor. Do not give anything by mouth to an unconscious person.

IF ON SKIN OR CLOTHING: Take off contaminated clothing. Rinse skin immediately with plenty of water for 15-20 minutes. Call a poison control center or doctor for treatment advice.
IF INHALED: Move person to fresh air. If person is not breathing, call 911 or an ambulance; then give artificial respiration, preferably mouth-to-mouth if possible. Call a poison control center or doctor for further treatment advice.

• Have the product container or label with you when calling a poison control center or doctor or going for treatment. • For additional information in case of emergency call toll free 1-877-424-7452.

For additional Precautionary Statements see inside booklet.

Personal Protective Equipment:

All mixers, loaders, applicators, flaggers, and other handlers must wear:

• Protective eyewear (goggles, face shield, or safety glasses).

• Long-sleeved shirt and long pants.

• Chemical-resistant gloves made of any waterproof material when applying with any handheld nozzle or equipment, mixing

  or loading, cleaning up spills or equipment, or otherwise exposed to the concentrate.

• Shoes and socks.

• Chemical-resistant apron when mixing or loading, cleaning up spills or equipment, or otherwise exposed to the

  concentrate.

  See engineering controls for additional requirements.

  Discard clothing or other absorbent materials that have been drenched or heavily contaminated with this product's concentrate. Do not reuse them. Follow manufacturer's instructions for cleaning or maintaining PPE. If no such instructions for washables exist, use detergent and hot water. Keep and wash PPE separately from other laundry. After each day’s use, clothing or PPE must not be reused until it has been cleaned.

  Engineering controls statement:

  If this container contains 5 gallons or more in capacity, do not pour product from this container. A mechanical system (pump and probe or spigot) must be used in transferring the contents of this container. If the contents of a non-refillable pesticide container are emptied, the probe must be rinsed before removal. If the mechanical system is used in a manner that meets the requirements listed in the Worker Protection Standard (WPS) for agricultural pesticides [40 CFR 170.240 (d)(4-6)], the handler PPE requirements may be reduced or modified as specified in the WPS.

  Pilots must use an enclosed cockpit that meets the requirements listed in the WPS for agricultural pesticides [40 CFR 170.240(d)(6)].

  When handlers use closed systems, enclosed cabs, or aircraft, in a manner that meets the requirements listed in the Worker Protection Standard (WPS) for agricultural pesticides [40 CFR 170.240 (d) (4-6)], the handler PPE requirements may be reduced or modified as specified in the WPS.

  ENVIRONMENTAL HAZARDS

  This product may be toxic to fish and aquatic invertebrates. For terrestrial uses: Do not apply directly to water, to areas where surface water is present, or to intertidal areas below the mean high water mark except as noted elsewhere on this label. Drift and runoff may be hazardous to aquatic invertebrates and non-target plants in water adjacent to treated areas. Do not contaminate water when disposing of equipment washwaters or rinsate.

  For aquatic uses: Fish breathe dissolved oxygen in the water and decaying weeds also use oxygen. When treating continuous, dense weed masses, it may be appropriate to treat only part of the infestation at a time. For example, apply the product in lanes separated by untreated strips that can be treated after vegetation in treated lanes has disintegrated. During the growing season, weeds decompose in a 2 to 3 week period following treatment. Begin treatment along the shore and proceed outwards in bands to allow fish to move into untreated areas. Waters having limited and less dense weed infestations may not require partial treatments.

  This chemical has properties and characteristics associated with chemicals detected in groundwater. The use of this chemical in areas where soils are permeable, particularly where the water table is shallow, may result in groundwater contamination.

2

Application around a cistern or well may result in contamination of drinking water or groundwater.

Most cases of groundwater contamination involving phenoxy herbicide such as 2,4-D have been associated with mixing/loading and disposal sites. Caution should be exercised when handling 2,4-D pesticides at such sites to prevent contamination of groundwater supplies. Use of closed systems for mixing and transferring this pesticide will reduce the probability of spills. Placement of mixing/loading equipment on an impervious pad to contain spills will help prevent groundwater contamination.

DIRECTIONS FOR USE

It is a violation of Federal Law to use this product in a manner inconsistent with its label. Do not apply this product in a way that will contact workers or other persons, either directly or through drift. Only protected handlers may be in the area during application. For any requirements specific to your State or Tribe, consult the agency responsible for pesticide regulation.

Use of this product in certain portions of California, Oregon and Washington is subject to the January 22, 2004 Order for injunctive relief in Washington Toxics Coalition, et al. v. EPA, C01-0132C, (W.D. WA). For further information, please refer to EPA Web Site: http://www.epa.gov/espp.

3

sumac, willow.
* These species may require repeat treatments and/or the higher rate. ** Control of pigweeds in the Texas and Oklahoma High

Plains may be difficult.

USE DIRECTIONS
Unless noted otherwise under individual DIRECTIONS section, for aerial application, apply the specified amount in a minimum

of 2 gallons of water per acre. For ground application, apply the specified amount in a minimum of 5 gallons of water per acre. Use more water for both methods when adverse growing conditions are present.

AQUATIC WEEDS

Alligatorweed, parrotfeather, water hyacinth, water lily, water primrose

4

WEED LIST

Shredder Amine 4 will control these plants and other 2,4-D susceptible species:

ANNUAL AND BIENNIAL WEEDS
Annual fanweeed (field pennycress), annual yellow sweet clover, * beggarticks, bull thistle, burdock, carpetweed, chickweed, cocklebur, coffeeweed, common mullein, common evening primrose, cornflower, croton, galinsoga, goatsbeard, hemp, henbit, jewelweed, jimsonweed * knotweed, * kochia, lambsquarters, mallow (Venice, dwarf, little), marshelder, morningglory (common, ivy, wooly) musk thistle, mustards (except blue), pennycress, pepperweed (field), ** pigweeds, poorjoe (wooly plantain), * prickly lettuce, puncturevine, purslane, ragweed (common, giant), rough fleabane, rush, Russian thistle, salsify, sheperdspurse, * stinkweed, smartweeds (annual), sowthistle (annual or spiny), sunflower, tansymustard, tumbleweed, *

velvetleaf, vetches, water primrose, * wild carrot, wild lettuce, wild parsnips, wild radish, wild sweet potato. PERENNIAL WEEDS

* Alfalfa, * bindweeds (hedge, field and European), blue lettuce, * broom snakeweed, buckhorn plantain, buttercup, * Canada thistle, catnip, chamise, chicory, climbing milkweed, common duckweed, curly indigo, dandelion, * docks, * dogbanes, * goldenrod, * ground ivy, * hawkweed (orange), * hoary cress, * Jerusalem artichoke, locoweed * many-flowered aster, milkvetch, * nettles, nutgrass, plantains, poison ivy, pokeweed, sheep sorrel, sicklepod, sneezeweed (bitter), sowthistle (perennial), * tansy ragwort, * vervains, * wild garlic, * wild onion, witchweed, wormwood, yellow rocket, yellow starthistle.

* BRUSH

Boxelder, buckbrush, coyotebrush, elderberry, manzanita, rabbitbrush, sagebrush (coastal, big, sand), sand shinnery oak,

5 Band Treatment: If only bands or rows are treated, leaving middles untreated, the dosage and spray volume per crop acre are reduced proportionately. For example, treating a 12-inch band where the row spacing is 36 inches would require 1/3 of the

recommended broadcast rate per acre (12 inches divided by 36 inches = 1/3).

Band width in inches Row width in inches

X Broadcast volume per acre = Band volume per acre

DO NOT apply with high spray pressures, hollow cone or other nozzle types that produce small spray droplets which may drift. Avoid spray drift by making applications when conditions such as wind, air stability and temperature inversions are not a factor. The use of a suitable drift control agent at the proper rate will aid in the reduction of spray drift. Apply when weather is warm and plants are rapidly growing. Cold weather or dry conditions may cause poor results. DO NOT apply if rain is expected within 6 hours. Consult your local agronomist or Extension specialist for specific use and crop tolerance situations. Do not apply this product through any type of irrigation system.

RESISTANCE MANAGEMENT

Shredder Amine 4 is a Group 4 herbicide. Any weed population may contain or develop plants naturally resistant to Shredder Amine 4 or other Group 4 herbicides. Weed species with acquired resistance to Group 4 may eventually dominate the weed population if Group 4 herbicides are used repeatedly in the same field or in successive years as the primary method of control for targeted species. This may result in partial or total loss of control of those species by Shredder Amine 4 or other Group 4 herbicides.

To delay herbicide resistance consider:

• Avoiding the consecutive use of Shredder Amine 4 or other target site of action Group 4 herbicides that have a

  similar target site of action, on the same weed species.

• Using tank-mixtures or premixes with herbicides from different target site of action Groups as long as the involved

  products are all registered for the same use, have different sites of action, and are both effective at the tank mix or

  prepack rate on the weed(s) of concern.

• Basing herbicide use on a comprehensive IPM program.

• Monitoring treated weed populations for loss of field efficacy.

• Contacting your local extension specialist, certified crop advisors, and/or Winfield Solutions, LLC representative for

  herbicide resistance management and/or integrated weed management recommendations for specific crops and resistant weed biotypes.

  TANK MIXES

  It is the pesticide user’s responsibility to ensure that all products used in tank mixtures are registered for the intended use. Users must follow the most restrictive directions for use and precautionary statements of each product in the tank mixture.

  SPRAY DRIFT MANAGEMENT

  A variety of factors including weather conditions (e.g., wind direction, wind speed, temperature, and relative humidity) and method of application (e.g., ground, aerial, airblast, chemigation) can influence pesticide drift. The applicator must evaluate all factors and make appropriate adjustments when applying this product.

  Droplet Size

  When applying sprays that contain 2,4-D as the sole active ingredient, or when applying sprays that contain 2,4-D mixed with active ingredients that require a Coarse or coarser spray, apply only as a Coarse or coarser spray (ASAE standard 572) or a volume mean diameter of 385 microns or greater for spinning atomizer nozzles.

  When applying sprays that contain 2,4-D mixed with other active ingredients that require a Medium or more fine spray, apply only as a Medium or coarser spray (ASAE standard 572) or a volume mean diameter of 300 microns or greater for spinning atomizer nozzles.

  Wind Speed

  Do not apply at wind speeds greater than 15 mph. Only apply this product if the wind direction favors on-target deposition and there are not sensitive areas (including, but not limited to, residential areas, bodies of water, known habitat for non-target

6

species, non-target crops) within 250 feet downwind. If applying a Medium spray, leave one swath unsprayed at the downwind edge of the treated field.

Temperature Inversions

If applying at wind speeds less than 3 mph, the applicator must determine if:
a) conditions of temperature inversion exist, or
b) stable atmospheric conditions exist at or below nozzle height. Do not make applications into areas of temperature inversions or stable atmospheric conditions.

Susceptible Plants

Do not apply under circumstances where spray drift may occur to food, forage, or other plantings that might be damaged or crops thereof rendered unfit for sale, use or consumption. Susceptible crops include, but are not limited to, cotton, okra, flowers, grapes (in growing stage), fruit trees (foliage), soybeans (vegetative stage), ornamentals, sunflowers, tomatoes, beans, and other vegetables, or tobacco. Small amounts of spray drift that might not be visible may injure susceptible broadleaf plants.

Other State and Local Requirements

Applicators must follow all state and local pesticide drift requirements regarding application of 2,4-D herbicides. Where states have more stringent regulations, they must be observed.

Equipment

All aerial and ground application equipment must be properly maintained and calibrated using appropriate carriers or surrogates.

Additional requirements for aerial applications:

The boom length must not exceed 75% of the wingspan or 90% of the rotor blade diameter. Release spray at the lowest height consistent with efficacy and flight safety. Do not release spray at a height greater than 10 feet above the crop canopy unless a greater height is required for aircraft safety. This requirement does not apply to forestry or rights-of-way applications. When applications are made with a crosswind, the swath will be displaced downwind. The applicator must compensate for this by adjusting the path of the aircraft upwind.

Additional requirements for ground boom application:

Do not apply with a nozzle height greater than 4 feet above the crop canopy.

MIXING INSTRUCTIONS
WATER BASED SPRAY -- Fill the equipment half full of water, agitate while adding this product; then add the rest of the water. NITROGEN FERTILIZER: Weed and feed applications for corn, small grains, grasses grown for seed or grass pastures according to label use rates. Add half the fertilizer to the tank, and then add recommended label amount of Shredder Amine 4 per acre. Agitate constantly and vigorously and finish filling the spray tank with fertilizer. Apply as soon as possible, agitating constantly. Do not hold spray mixture overnight. If incompatibility is a problem, the use of COMPLETE COMPATIBILITY® agent at the recommended label rate may correct the problem. Fertilize according to the recommendations of your supplier or your Extension specialist. Herbicide foliage contact burning may occur as a result of fertilizer use. Lower use rates and

concentrations will reduce this problem.
Adjuvants for Preemergence and Preplant Applications: A non-ionic surfactant such as PREFERENCE® or a crop oil concentrate may be added to the spray solution when this product is applied preemergence or preplant to increase control of large or difficult to control weeds. Crop oil concentrates must contain at least 17% emulsifier, and should be used at 1% volume/volume (1 gallon per 100 gallons of spray solution). Non-ionic surfactants should be used at a 0.25% volume/volume (1 quart per 100 gallons of spray solution). Wash spray equipment thoroughly with PROTANK® cleaner after using this product. When cleaning, do not pour washwater on the ground: spray or drain over a large area away from wells or other water sources. Apply the recommended amount of 2,4-D per acre regardless of the amount of diluent used.

When an adjuvant is to be used with this product, Winfield Solutions, LLC recommends the use of a Chemical Producers

and Distributors Association certified adjuvant.
APPLES, PEARS, STONE FRUIT AND NUT ORCHARDS (Do not use in California)

7

ASPARAGUS

CORN – FIELD, SWEET AND POP

* Use higher rate on hard-to-kill weeds and existing cover crops such as alfalfa. Do not perform tillage for at least 7 days after application. Do not use on sandy soils or unacceptable crop injury may result.

SOYBEANS

8

SMALL GRAINS - Not underseeded with legumes

9